tag:blogger.com,1999:blog-3300702123878659843.post2249034828439457127..comments2024-03-26T05:25:50.831-04:00Comments on University of Ottawa NMR Facility Blog: NOESY: Small Molecules vs Large MoleculesGlenn Faceyhttp://www.blogger.com/profile/05146575170575279335noreply@blogger.comBlogger2125tag:blogger.com,1999:blog-3300702123878659843.post-47817372535682863622011-01-20T08:34:42.233-05:002011-01-20T08:34:42.233-05:00Anonymous.
Thank you for the comment.
Molecules ...Anonymous.<br /><br />Thank you for the comment.<br /><br />Molecules with short correlation times for rotational diffusion (such that the product of the correlation time and the angular Larmor frequency is much less than 1), will yeild NOESY spectra with cross peaks antiphase with respect to the diagonals. Your metal complex must fall within this regime.<br /><br />GlennGlenn Faceyhttps://www.blogger.com/profile/05146575170575279335noreply@blogger.comtag:blogger.com,1999:blog-3300702123878659843.post-61803640273246524422011-01-19T12:53:32.123-05:002011-01-19T12:53:32.123-05:00Thanks this is helpful!
So If I had a metal compl...Thanks this is helpful!<br /><br />So If I had a metal complex with M.W ~ 550, would I see both positive and negative NOE's for protons that are close in proximity? Because this is what I am observing.Anonymousnoreply@blogger.com